Publication detail

Matrix effects in the neutralization of He ions at a metal surface containing oxygen

KÜRNSTEINER, P. STEINBERGER, R. PRIMETZHOFER, D. GOEBL, D. WAGNER, T. DRUCKMÜLLEROVÁ, Z. ZEPPENFELD, P. BAUER, P.

Czech title

Matrix effects in the neutralization of He ions at a metal surface containing oxygen

English title

Matrix effects in the neutralization of He ions at a metal surface containing oxygen

Type

journal article - other

Language

en

Original abstract

Charge exchange between He ions and a Ni(111) surface containing oxygen was studied by Low-Energy Ion Scattering, using 1.25 keV He+ as primary ions. The energy resolved yield of positive ions was detected after backscattering from Ni or O for different exposures of Ni(111) to molecular oxygen. Pronounced changes in the neutralization efficiency due to the presence of oxygen are observed for both, the adsorbate phase at low oxygen dose, and the NiO phase at high dose. The presence of O in the surface makes resonant charge transfer in a close collision possible. Evidence for a strong matrix effect is found: O in NiO neutralizes much more efficiently than O in the adsorbate phase. Independently, the different interaction stages of Ni–O and the surface structure were monitored by Photoelectron-Emission-Microscopy and Low-Energy Electron Diffraction.

Czech abstract

Charge exchange between He ions and a Ni(111) surface containing oxygen was studied by Low-Energy Ion Scattering, using 1.25 keV He+ as primary ions. The energy resolved yield of positive ions was detected after backscattering from Ni or O for different exposures of Ni(111) to molecular oxygen. Pronounced changes in the neutralization efficiency due to the presence of oxygen are observed for both, the adsorbate phase at low oxygen dose, and the NiO phase at high dose. The presence of O in the surface makes resonant charge transfer in a close collision possible. Evidence for a strong matrix effect is found: O in NiO neutralizes much more efficiently than O in the adsorbate phase. Independently, the different interaction stages of Ni–O and the surface structure were monitored by Photoelectron-Emission-Microscopy and Low-Energy Electron Diffraction.

English abstract

Charge exchange between He ions and a Ni(111) surface containing oxygen was studied by Low-Energy Ion Scattering, using 1.25 keV He+ as primary ions. The energy resolved yield of positive ions was detected after backscattering from Ni or O for different exposures of Ni(111) to molecular oxygen. Pronounced changes in the neutralization efficiency due to the presence of oxygen are observed for both, the adsorbate phase at low oxygen dose, and the NiO phase at high dose. The presence of O in the surface makes resonant charge transfer in a close collision possible. Evidence for a strong matrix effect is found: O in NiO neutralizes much more efficiently than O in the adsorbate phase. Independently, the different interaction stages of Ni–O and the surface structure were monitored by Photoelectron-Emission-Microscopy and Low-Energy Electron Diffraction.

Keywords in Czech

Low energy ion scattering; LEIS; Charge exchange processes; Surface composition analysis; Metal oxide

Keywords in English

Low energy ion scattering; LEIS; Charge exchange processes; Surface composition analysis; Metal oxide

RIV year

2012

Released

13.12.2012

ISSN

0039-6028

Volume

609

Number

1

Pages from–to

167–171

Pages count

5

BIBTEX


@article{BUT96555,
  author="Phillip {Kürnsteiner} and Roland {Steinberger} and Daniel {Primetzhofer} and Dominik {Goebl} and Thorsten {Wagner} and Zdena {Rudolfová} and Peter {Zeppenfeld} and P. {Bauer},
  title="Matrix effects in the neutralization of He ions at a metal surface containing oxygen",
  year="2012",
  volume="609",
  number="1",
  month="December",
  pages="167--171",
  issn="0039-6028"
}