Publication detail

Microwave assisted green synthesis of Ag doped CuO NPs anchored on GO-sheets for high performance photocatalytic and antimicrobial applications

Mariadhas, Jarvin Panchu, Sarojini Jeeva Swart, Hendrik C. Rosaline, Daniel Rani Murugadoss, Govindasamy Govindarajan, Durai Kheawhom, Soorathep Inbanathan, Savairoyan Stephen Rajkumar Bokhari, Awais Chuah, Lai Fatt

English title

Microwave assisted green synthesis of Ag doped CuO NPs anchored on GO-sheets for high performance photocatalytic and antimicrobial applications

Type

journal article in Web of Science

Language

en

Original abstract

Dangerous non-biodegradable compounds are released into the environment due to the increased human population and industrialization. A simple green synthesis approach of novel silver (Ag)-doped copper oxide (CuO) anchored graphene oxide (GO) nanosheets (Ag-CuO@GO) via energy-efficient microwave heating method has been developed for photocatalytic and antimicrobial applications. Tea extract is used as a capping and reducing agent. The prepared Ag-CuO@GO nanocomposites (NCs) used for photocatalytic and antimicrobial activities are investigated systematically. The highly crystalline, wellinterconnected Ag-CuO nanoparticles (NPs) over GO provide an enhanced surface area of 24.1 m2/g and an efficient pore diameter of 15.1 nm with more active sites. A reduced optical bandgap (Eg) of 1.48 eV obtained for the Ag-CuO@GO NCs, less than that of the bare and Ag-CuO, indicates that it can function as an efficient photocatalyst by harvesting solar energy. As demonstrated by the suppressed PL of the ternary Ag-CuO@GO nanocatalysts, additional of Ag and GO can efficiently separate the charge carriers. Ag-CuO@GO exhibited an 89% increase in the dye removal rate of MB dye and high antimicrobial activity against S.aureus, E.coli and Candida albicans that that of bare CuO and binary NCs. The synthesized novel Ag-CuO@GO NCs show promise as potential photocatalysts for the pollutant degradation and antimicrobial activity.

English abstract

Dangerous non-biodegradable compounds are released into the environment due to the increased human population and industrialization. A simple green synthesis approach of novel silver (Ag)-doped copper oxide (CuO) anchored graphene oxide (GO) nanosheets (Ag-CuO@GO) via energy-efficient microwave heating method has been developed for photocatalytic and antimicrobial applications. Tea extract is used as a capping and reducing agent. The prepared Ag-CuO@GO nanocomposites (NCs) used for photocatalytic and antimicrobial activities are investigated systematically. The highly crystalline, wellinterconnected Ag-CuO nanoparticles (NPs) over GO provide an enhanced surface area of 24.1 m2/g and an efficient pore diameter of 15.1 nm with more active sites. A reduced optical bandgap (Eg) of 1.48 eV obtained for the Ag-CuO@GO NCs, less than that of the bare and Ag-CuO, indicates that it can function as an efficient photocatalyst by harvesting solar energy. As demonstrated by the suppressed PL of the ternary Ag-CuO@GO nanocatalysts, additional of Ag and GO can efficiently separate the charge carriers. Ag-CuO@GO exhibited an 89% increase in the dye removal rate of MB dye and high antimicrobial activity against S.aureus, E.coli and Candida albicans that that of bare CuO and binary NCs. The synthesized novel Ag-CuO@GO NCs show promise as potential photocatalysts for the pollutant degradation and antimicrobial activity.

Keywords in English

Ag-CuO@GO NCs; Antimicrobial activity; Green synthesis; Photocatalytic activity

Released

25.12.2023

Publisher

ELSEVIER SCIENCE INCSTE 800, 230 PARK AVE, NEW YORK, NY 10169

Location

ELSEVIER SCIENCE INCSTE 800, 230 PARK AVE, NEW YORK, NY 10169

ISSN

1226-086X

Number

128

Pages from–to

383–395

Pages count

13

BIBTEX


@article{BUT187681,
  author="Syed Awais Ali Shah {Bokhari},
  title="Microwave assisted green synthesis of Ag doped CuO NPs anchored on GO-sheets for high performance photocatalytic and antimicrobial applications",
  year="2023",
  number="128",
  month="December",
  pages="383--395",
  publisher="ELSEVIER SCIENCE INCSTE 800, 230 PARK AVE, NEW YORK, NY 10169",
  address="ELSEVIER SCIENCE INCSTE 800, 230 PARK AVE, NEW YORK, NY 10169",
  issn="1226-086X"
}