Array
(
[system_kategorie] => PU
[zakladni_udaje] => Array
(
[vysledek_id] => 187483
[vysledek_rok] => 2023
[duvernost_udaju_id] => S
[nazev] => Activated waste cotton cellulose as renewable fuel and value-added chemicals: Thermokinetic analysis, coupled pyrolysis with gas chromatography and mass spectrometry
[nazev_orig] => Activated waste cotton cellulose as renewable fuel and value-added chemicals: Thermokinetic analysis, coupled pyrolysis with gas chromatography and mass spectrometry
[popis] =>
The bioenergy potential of waste textile cotton cellulose (BOC) and the activated waste textile cotton cellulose by H3PO4 (BOP) were assessed in this study. BOC and BOP were pyrolyzed in TG at four heating rates. The thermal weight-loss process of BOC and BOP can be separated into drying stage, rapid pyrolysis stage and carbonization stage. The kinetic and thermodynamic parameters of the pyrolysis reaction were evaluated using an iso-conversion model. The Ea, Delta H and Delta G values of BOC are 84.79-206.79 kJ mol(-1), 159.85-318.88 kJ mol(-1) and 357.72-359.16 kJ mol-1, respectively. The Ea, & UDelta;H and & UDelta;G values of BOP are 101.81-453.85 kJ mol -1, 169.11-389.47 kJ mol-1 and 257 similar to 335.78 kJ mol-1, respectively. Py-GC/MS analysis illustrated that the peak area percentages of the products of BOC/BOP, including Glucopyranose, Ketones, Cycloalkane, Aromatic, Furan, Aliphatic, CO2, and others, were 47.7%/5%, 4.66%/30.41%, 0%/27.12%, 16.64%/3.22%, 8.55%/12.44%, 12.75%/13.29%, 4.19%/3.91% and 5.51%/4.61%, respectively. Compared with BOC, the low-quality products of BOP, Glucopyranose and Aromatic, decreased from 47.7% to 16.64%-5% and 3.22%, respectively, and the high-quality products, Ketone and Cycloalkane, increased from 4.66% to 0%-30.41% and 27.12%, respectively. The complexity of bio-oil of BOP is reduced, which gives a positive prospect for the purification of backward position.
[popis_orig] =>
The bioenergy potential of waste textile cotton cellulose (BOC) and the activated waste textile cotton cellulose by H3PO4 (BOP) were assessed in this study. BOC and BOP were pyrolyzed in TG at four heating rates. The thermal weight-loss process of BOC and BOP can be separated into drying stage, rapid pyrolysis stage and carbonization stage. The kinetic and thermodynamic parameters of the pyrolysis reaction were evaluated using an iso-conversion model. The Ea, Delta H and Delta G values of BOC are 84.79-206.79 kJ mol(-1), 159.85-318.88 kJ mol(-1) and 357.72-359.16 kJ mol-1, respectively. The Ea, & UDelta;H and & UDelta;G values of BOP are 101.81-453.85 kJ mol -1, 169.11-389.47 kJ mol-1 and 257 similar to 335.78 kJ mol-1, respectively. Py-GC/MS analysis illustrated that the peak area percentages of the products of BOC/BOP, including Glucopyranose, Ketones, Cycloalkane, Aromatic, Furan, Aliphatic, CO2, and others, were 47.7%/5%, 4.66%/30.41%, 0%/27.12%, 16.64%/3.22%, 8.55%/12.44%, 12.75%/13.29%, 4.19%/3.91% and 5.51%/4.61%, respectively. Compared with BOC, the low-quality products of BOP, Glucopyranose and Aromatic, decreased from 47.7% to 16.64%-5% and 3.22%, respectively, and the high-quality products, Ketone and Cycloalkane, increased from 4.66% to 0%-30.41% and 27.12%, respectively. The complexity of bio-oil of BOP is reduced, which gives a positive prospect for the purification of backward position.
[klicova_slova] => Kinetic parameters; Py-GC/MS; Pyrolysis; Thermodynamic analysis; Waste textile cotton cellulose
[klicova_slova_orig] => Kinetic parameters; Py-GC/MS; Pyrolysis; Thermodynamic analysis; Waste textile cotton cellulose
[url] => https://www.sciencedirect.com/science/article/pii/S0360544223017358?via%3Dihub
[oecd_obor_id] => 20303
[odpovedny_utvar_id] => 22480
[originalni_jazyk] => en
[vycet_osob] => Yu, Zhang; Ahmad, Muhammad Sajjad; Shen, Boxiong; Li, Yingna; Ibrahim, Muhammad; Bokhari, Awais; Klemes, Jiri Jaromir
[pocet_tvurcu] => 7
[poznamka] =>
[zverejneno] => 1
[vysledek_stav_id] => 3
[neautorsky_vysledek] => 0
[vlozil] => Informační systém Automat
[upravil] => Informační systém Automat
[vysledek_kategorie_id] => PV
[kategorie_nazev] => Publication results
[vysledek_druh_id] => ARTWOS
[druh_nazev] => WoS Article
[druh_popis] => Peer-reviewed article included in Web of Science database as as an “Article”, “Review” or “Letter”
[stav] => Approved
[identifikator] => ISSN 0360-5442
[identifikator_popis] => ISSN - Energy (GB)
[nadrazena_soucast_id] => 4
[nadrazena_soucast_zkratka] => FME
[nadrazena_soucast_nazev] => Faculty of Mechanical Engineering
[odpovedny_utvar_nazev] => Sustainable process integration laboratory
[odpovedny_utvar_zkratka] => NETME SPIL
[kod_doi] => 10.1016/j.energy.2023.128341
[kod_dspace] =>
[wos] => 001052281200001
[eid] => 2-s2.0-85165694530
[citace_text] => Yu, Zhang; Ahmad, Muhammad Sajjad; Shen, Boxiong; Li, Yingna; Ibrahim, Muhammad; Bokhari, Awais; Klemes, Jiri Jaromir. Activated waste cotton cellulose as renewable fuel and value-added chemicals: Thermokinetic analysis, coupled pyrolysis with gas chromatography and mass spectrometry. Energy, 2023, no. 283, 12 p. ISSN: 0360-5442.
[citace_html] => Yu, Zhang; Ahmad, Muhammad Sajjad; Shen, Boxiong; Li, Yingna; Ibrahim, Muhammad; Bokhari, Awais; Klemes, Jiri Jaromir. Activated waste cotton cellulose as renewable fuel and value-added chemicals: Thermokinetic analysis, coupled pyrolysis with gas chromatography and mass spectrometry. Energy, 2023, no. 283, 12 p. ISSN: 0360-5442.
[citace_bibtex] => @article{BUT187483,
author="Yu, Zhang and Ahmad, Muhammad Sajjad and Shen, Boxiong and Li, Yingna and Ibrahim, Muhammad and Bokhari, Awais and Klemes, Jiri Jaromir",
title="Activated waste cotton cellulose as renewable fuel and value-added chemicals: Thermokinetic analysis, coupled pyrolysis with gas chromatography and mass spectrometry",
journal="Energy",
year="2023",
number="283",
pages="12",
doi="10.1016/j.energy.2023.128341",
issn="0360-5442",
url="https://www.sciencedirect.com/science/article/pii/S0360544223017358?via%3Dihub"
}
[znamka] =>
[nazev_en] => Activated waste cotton cellulose as renewable fuel and value-added chemicals: Thermokinetic analysis, coupled pyrolysis with gas chromatography and mass spectrometry
[popis_en] =>
The bioenergy potential of waste textile cotton cellulose (BOC) and the activated waste textile cotton cellulose by H3PO4 (BOP) were assessed in this study. BOC and BOP were pyrolyzed in TG at four heating rates. The thermal weight-loss process of BOC and BOP can be separated into drying stage, rapid pyrolysis stage and carbonization stage. The kinetic and thermodynamic parameters of the pyrolysis reaction were evaluated using an iso-conversion model. The Ea, Delta H and Delta G values of BOC are 84.79-206.79 kJ mol(-1), 159.85-318.88 kJ mol(-1) and 357.72-359.16 kJ mol-1, respectively. The Ea, & UDelta;H and & UDelta;G values of BOP are 101.81-453.85 kJ mol -1, 169.11-389.47 kJ mol-1 and 257 similar to 335.78 kJ mol-1, respectively. Py-GC/MS analysis illustrated that the peak area percentages of the products of BOC/BOP, including Glucopyranose, Ketones, Cycloalkane, Aromatic, Furan, Aliphatic, CO2, and others, were 47.7%/5%, 4.66%/30.41%, 0%/27.12%, 16.64%/3.22%, 8.55%/12.44%, 12.75%/13.29%, 4.19%/3.91% and 5.51%/4.61%, respectively. Compared with BOC, the low-quality products of BOP, Glucopyranose and Aromatic, decreased from 47.7% to 16.64%-5% and 3.22%, respectively, and the high-quality products, Ketone and Cycloalkane, increased from 4.66% to 0%-30.41% and 27.12%, respectively. The complexity of bio-oil of BOP is reduced, which gives a positive prospect for the purification of backward position.
[klicova_slova_en] => Kinetic parameters; Py-GC/MS; Pyrolysis; Thermodynamic analysis; Waste textile cotton cellulose
[vysledek_datum] => 2023-11-15T00:00:00+01:00
)
[specificke_udaje] => Array
(
[vysledek_publikace_id] => 150469
[vysledek_pristupnost_id] => L
[vysledek_id] => 187483
[periodikum_id] => 1224
[periodikum_issn] => 0360-5442
[periodikum_svazek] =>
[periodikum_svazek_cislo] => 283
[isbn] =>
[kniha_nazev] =>
[edice] =>
[forma_vydani_id] => P
[kniha_pocet_stran] =>
[kniha_pocet_vytisku] =>
[zpusob_publikovani_id] => C
[strana_od] =>
[strana_do] =>
[pocet_stran] => 12
[nakladatel] => PERGAMON-ELSEVIER SCIENCE LTDTHE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND
[cislo_vydani] =>
[misto_vydani] =>
PERGAMON-ELSEVIER SCIENCE LTDTHE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND
[datum_zverejneni] =>
[strankovano] =>
[periodikum_nazev] => Energy
[periodikum_stat_vydavatele] => United Kingdom of Great Britain and Northern Ireland
[technicke_parametry] =>
[ekonomicke_parametry] =>
[navazane_akce] => Array
(
)
)
)
Array
(
[typ] => PU
[page_title_red] => Publication detail
[released] => 2023-11-15
[language] => en
[bibtex] => @article{BUT187483,
author="Yu, Zhang and Ahmad, Muhammad Sajjad and Shen, Boxiong and Li, Yingna and Ibrahim, Muhammad and Bokhari, Awais and Klemes, Jiri Jaromir",
title="Activated waste cotton cellulose as renewable fuel and value-added chemicals: Thermokinetic analysis, coupled pyrolysis with gas chromatography and mass spectrometry",
journal="Energy",
year="2023",
number="283",
pages="12",
doi="10.1016/j.energy.2023.128341",
issn="0360-5442",
url="https://www.sciencedirect.com/science/article/pii/S0360544223017358?via%3Dihub"
}
[title_orig] => Activated waste cotton cellulose as renewable fuel and value-added chemicals: Thermokinetic analysis, coupled pyrolysis with gas chromatography and mass spectrometry
[abstract_orig] => The bioenergy potential of waste textile cotton cellulose (BOC) and the activated waste textile cotton cellulose by H3PO4 (BOP) were assessed in this study. BOC and BOP were pyrolyzed in TG at four heating rates. The thermal weight-loss process of BOC and BOP can be separated into drying stage, rapid pyrolysis stage and carbonization stage. The kinetic and thermodynamic parameters of the pyrolysis reaction were evaluated using an iso-conversion model. The Ea, Delta H and Delta G values of BOC are 84.79-206.79 kJ mol(-1), 159.85-318.88 kJ mol(-1) and 357.72-359.16 kJ mol-1, respectively. The Ea, & UDelta;H and & UDelta;G values of BOP are 101.81-453.85 kJ mol -1, 169.11-389.47 kJ mol-1 and 257 similar to 335.78 kJ mol-1, respectively. Py-GC/MS analysis illustrated that the peak area percentages of the products of BOC/BOP, including Glucopyranose, Ketones, Cycloalkane, Aromatic, Furan, Aliphatic, CO2, and others, were 47.7%/5%, 4.66%/30.41%, 0%/27.12%, 16.64%/3.22%, 8.55%/12.44%, 12.75%/13.29%, 4.19%/3.91% and 5.51%/4.61%, respectively. Compared with BOC, the low-quality products of BOP, Glucopyranose and Aromatic, decreased from 47.7% to 16.64%-5% and 3.22%, respectively, and the high-quality products, Ketone and Cycloalkane, increased from 4.66% to 0%-30.41% and 27.12%, respectively. The complexity of bio-oil of BOP is reduced, which gives a positive prospect for the purification of backward position.
[title_cs] =>
[title_en] => Activated waste cotton cellulose as renewable fuel and value-added chemicals: Thermokinetic analysis, coupled pyrolysis with gas chromatography and mass spectrometry
[keywords_cs] =>
[keywords_en] => Kinetic parameters; Py-GC/MS; Pyrolysis; Thermodynamic analysis; Waste textile cotton cellulose
[pub_type] => WoS Article
[quotations] => Yu, Zhang; Ahmad, Muhammad Sajjad; Shen, Boxiong; Li, Yingna; Ibrahim, Muhammad; Bokhari, Awais; Klemes, Jiri Jaromir
[publisher] => PERGAMON-ELSEVIER SCIENCE LTDTHE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND
[location] => PERGAMON-ELSEVIER SCIENCE LTDTHE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND
[issn] => 0360-5442
[isbn] =>
[volume] =>
[number] => 283
[pages] => 12
[book] =>
[journal] => Energy
)
Publication detail
Activated waste cotton cellulose as renewable fuel and value-added chemicals: Thermokinetic analysis, coupled pyrolysis with gas chromatography and mass spectrometry
Yu, Zhang Ahmad, Muhammad Sajjad Shen, Boxiong Li, Yingna Ibrahim, Muhammad Bokhari, Awais Klemes, Jiri Jaromir
English title
Activated waste cotton cellulose as renewable fuel and value-added chemicals: Thermokinetic analysis, coupled pyrolysis with gas chromatography and mass spectrometry
Type
WoS Article
Language
en
Original abstract
The bioenergy potential of waste textile cotton cellulose (BOC) and the activated waste textile cotton cellulose by H3PO4 (BOP) were assessed in this study. BOC and BOP were pyrolyzed in TG at four heating rates. The thermal weight-loss process of BOC and BOP can be separated into drying stage, rapid pyrolysis stage and carbonization stage. The kinetic and thermodynamic parameters of the pyrolysis reaction were evaluated using an iso-conversion model. The Ea, Delta H and Delta G values of BOC are 84.79-206.79 kJ mol(-1), 159.85-318.88 kJ mol(-1) and 357.72-359.16 kJ mol-1, respectively. The Ea, & UDelta;H and & UDelta;G values of BOP are 101.81-453.85 kJ mol -1, 169.11-389.47 kJ mol-1 and 257 similar to 335.78 kJ mol-1, respectively. Py-GC/MS analysis illustrated that the peak area percentages of the products of BOC/BOP, including Glucopyranose, Ketones, Cycloalkane, Aromatic, Furan, Aliphatic, CO2, and others, were 47.7%/5%, 4.66%/30.41%, 0%/27.12%, 16.64%/3.22%, 8.55%/12.44%, 12.75%/13.29%, 4.19%/3.91% and 5.51%/4.61%, respectively. Compared with BOC, the low-quality products of BOP, Glucopyranose and Aromatic, decreased from 47.7% to 16.64%-5% and 3.22%, respectively, and the high-quality products, Ketone and Cycloalkane, increased from 4.66% to 0%-30.41% and 27.12%, respectively. The complexity of bio-oil of BOP is reduced, which gives a positive prospect for the purification of backward position.
@article{BUT187483,
author="Yu, Zhang and Ahmad, Muhammad Sajjad and Shen, Boxiong and Li, Yingna and Ibrahim, Muhammad and Bokhari, Awais and Klemes, Jiri Jaromir",
title="Activated waste cotton cellulose as renewable fuel and value-added chemicals: Thermokinetic analysis, coupled pyrolysis with gas chromatography and mass spectrometry",
journal="Energy",
year="2023",
number="283",
pages="12",
doi="10.1016/j.energy.2023.128341",
issn="0360-5442",
url="https://www.sciencedirect.com/science/article/pii/S0360544223017358?via%3Dihub"
}