Detail publikace

Effects of reagent purity on plasma electrolytic oxidation of titanium in an aluminate–phosphate electrolyte

ALIASGHARI, S. NĚMCOVÁ, A. ČÍŽEK, J. GHOLINIA, A. SKELDON, P. THOMPSON, G.

Anglický název

Effects of reagent purity on plasma electrolytic oxidation of titanium in an aluminate–phosphate electrolyte

Typ

článek v časopise ve Web of Science, Jimp

Jazyk

en

Originální abstrakt

The effect of reagent purity on AC plasma electrolytic oxidation of titanium in aluminate–phosphate-based electrolytes has been studied under constant rms current conditions. The resultant coatings were examined by high-resolution electron microscopy and X-ray diffraction, revealing rutile, Al2TiO5, alpha-Al2O3 and gamma-Al2O3, with an aluminium-enriched outer region and phosphorus-enriched band near the coating base. A lower purity of the electrolyte led to an erratic voltage response and delamination of coating material in scratch tests. A thin chlorine-enriched region near the substrate, attributed to the inward migration of chloride ions during coating growth, is suggested to be the cause of the delamination. Deliberate additions of chloride to the electrolyte resulted in highly porous coatings.

Anglický abstrakt

The effect of reagent purity on AC plasma electrolytic oxidation of titanium in aluminate–phosphate-based electrolytes has been studied under constant rms current conditions. The resultant coatings were examined by high-resolution electron microscopy and X-ray diffraction, revealing rutile, Al2TiO5, alpha-Al2O3 and gamma-Al2O3, with an aluminium-enriched outer region and phosphorus-enriched band near the coating base. A lower purity of the electrolyte led to an erratic voltage response and delamination of coating material in scratch tests. A thin chlorine-enriched region near the substrate, attributed to the inward migration of chloride ions during coating growth, is suggested to be the cause of the delamination. Deliberate additions of chloride to the electrolyte resulted in highly porous coatings.

Klíčová slova anglicky

Titanium, Plasma electrolytic oxidation, Electron microscopy

Vydáno

08.03.2016

Nakladatel

Taylor & Francis

Místo

United Kingdom

ISSN

0020-2967

Ročník

94

Číslo

1

Strany od–do

32–42

Počet stran

11

BIBTEX


@article{BUT122852,
  author="Sepideh {Aliasghari} and Aneta {Němcová} and Jan {Čížek} and Ali {Gholinia} and Peter {Skeldon} and George {Thompson},
  title="Effects of reagent purity on plasma electrolytic oxidation of titanium in an aluminate–phosphate electrolyte",
  year="2016",
  volume="94",
  number="1",
  month="March",
  pages="32--42",
  publisher="Taylor & Francis",
  address="United Kingdom",
  issn="0020-2967"
}